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Synthesis of Mixed Arylalkyl Tertiary Phosphines via the Grignard Approach.
- Source :
-
Molecules . Jul2022, Vol. 27 Issue 13, p4253-N.PAG. 14p. - Publication Year :
- 2022
-
Abstract
- Trialkyl and triaryl phosphines are important classes of ligands in the field of catalysis and materials research. The wide usability of these low-valent phosphines has led to the design and development of new synthesis routes for a variety of phosphines. In the present work, we report the synthesis and characterization of some mixed arylalkyl tertiary phosphines via the Grignard approach. A new asymmetric phosphine is characterized extensively by multi-spectroscopic techniques. IR and UV–Vis spectra of some selected compounds are also compared and discussed. Density functional theory (DFT)-calculated results support the formation of the new compounds. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PHOSPHINES
*DENSITY functional theory
Subjects
Details
- Language :
- English
- ISSN :
- 14203049
- Volume :
- 27
- Issue :
- 13
- Database :
- Academic Search Index
- Journal :
- Molecules
- Publication Type :
- Academic Journal
- Accession number :
- 157998315
- Full Text :
- https://doi.org/10.3390/molecules27134253