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Facile synthesis, structure, and properties of Gd2O2Se.
- Source :
-
Journal of Solid State Chemistry . Aug2022, Vol. 312, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
-
Abstract
- Inorganic phosphors based on rare earth elements are commonly used as scintillation materials due to their high chemical and radiation resistance. In this work, we study gadolinium oxyselenide as a new phosphor material. The work describes a facile synthesis method for Gd 2 O 2 Se. Single crystal structure of this compound was determined for the first time: sp.gr. P ¯3 m 1 with a = 3.8911(4) Å and c = 6.8829(8) Å. Gd 2 O 2 Se is stable in the inert atmosphere and melts at 2075 ± 20 °C. This material is also stable when heated in air up to 720 °C. with the following oxidation and weight increase. This mass increase can be explained by the oxidation of Se2− to Se4+. Further temperature increase above 952°С leads to a sharp mass loss and the final mass of sample corresponds to full oxidation of Gd 2 O 2 Se to gadolinium oxide. The band gap of the material was estimated to be 3.6 eV. Photoluminescence spectrum for Gd 2 O 2 Se:Tb3+ shows the characteristic transitions in Tb3+ ion with the most intense green emission that corresponds 5D 4 → 7F J transitions. [Display omitted] • A powder of Gd 2 O 2 Se was obtained and the single crystal structure was determined: sp.gr. P ¯3 m 1, a = 3.89Å, c = 6.88 Å. • The melting point was found to be 2075 ± 20 °C. High air stability for this compound was demonstrated up to 720 °C. • The estimated value of the band gap is 3.6 eV. The photoluminescence of the Tb3+ doped sample was investigated. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00224596
- Volume :
- 312
- Database :
- Academic Search Index
- Journal :
- Journal of Solid State Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 157525697
- Full Text :
- https://doi.org/10.1016/j.jssc.2022.123224