Effect of antimony on characteristics of HgBa2CaCu2-xSbxO8+δ superconducting.

In this work, HgBa2CaCu2-xSbxO8+δ compounds with (x = 0.2, 0.4, 0.6 and 0.8) have been prepared by the solid-state reaction method. Structural, morphological, and electrical properties were investigated using X-ray diffraction (XRD) and scanning electron microscope (SEM) techniques. Using the 4-probe technique to study the effect of antimony-substitution for Copper on the electrical properties of HgBa2CaCu2-xSbxO8+δ (Hg-1212) phase was investigated by measuring the resistivity as a function of temperature. Results indicate that the addition of antimony (Sb) increases the volume fraction of the phase and changes the superconducting transition temperature Tc of the superconductor to a normal state. The dielectric loss factor and ac conductivity have been investigated at room temperature. It was found that dielectric properties decreased with increasing electric field frequency. It was observed that the best value was 0.8 of the Sb content. Generally, with increasing antimony content, at lower frequencies, higher dielectric criteria are achieved, while at higher frequencies, lower dielectric criteria are achieved. On the other hand, the dissipation of the energy in the dielectric is directly proportional to the dielectric loss factor. Considering this, the increase in the values of ac conductivity is increasing with an increased frequency range to 5 MHz. [ABSTRACT FROM AUTHOR]