Differences and origins of hydrocarbon generation characteristics between mudstone and shale in the Seventh Member of the Yanchang Formation, Ordos Basin, China.

Organic-rich black shale and dark-grey mudstone are widespread in the Seventh Member of the Yanchang Formation, Ordos Basin. There are obviously differences in geochemical characteristics and hydrocarbon generation potential between black shale and dark-grey mudstone. Based on the detailed organic geochemical examination, this paper reveals the differences in hydrocarbon generation processes and characteristics (activation energy and conversion rate of hydrocarbon generation) between dark-grey mudstone and black shale and the causes for the differences. Black shale is characterized by moderate to very high total organic carbon (TOC) contents (5.08%–39.39%) and its kerogen type belongs to type II 1 and type I. Dark-grey mudstone has a characteristic of low to moderate TOC contents (0.64%–7.35%) and its kerogen types are mainly composed of type II 2 and type II 1. The hydrocarbon generation activation energy of black shale mainly oscillates around 250–310 KJ/mol, and the corresponding hydrocarbon generation threshold is high (the simulated temperature is 400 °C). The process of hydrocarbon generation is characterized by fast conversion rate and short cycle. By contrast, the hydrocarbon generation activation energy of dark-grey mudstone has a wide range (170–360 KJ/mol), and the corresponding hydrocarbon generation threshold is low (the simulated temperature is 230 °C). The process of hydrocarbon generation is characterized by slow conversion rate and long cycle. The difference of hydrocarbon generation process and characteristics between black shale and dark-grey mudstone is mainly affected by macerals composition and organic matter source. The organic matter of black shale mainly originated from algae, and its macerals was mainly composed of alginite. The organic matter of dark-grey mudstone mainly originated from the mixture of algae and terrestrial higher plants (conifers), and its macerals was mainly composed of vitrinite, liptodetrinite and inertinite. The complex macerals composition and organic matter source make the activation energy distribution of dark-grey mudstone more dispersed than that of black shale. In addition, affected by the macerals (e.g sporinite and resinite) with low activation energy from terrestrial higher plants, the activation energy of dark-grey mudstone containing sporinite and resinite in the macerals is lower than black shale. Therefore, the dark-grey mudstone containing algae and terrestrial higher plants corresponds to low hydrocarbon generation threshold, slow conversion rate and long hydrocarbon generation cycle. The black shale containing a large number of algae corresponds to high hydrocarbon generation threshold, fast conversion rate and short hydrocarbon generation cycle. Moreover, the conversion rate of black shale containing radioactive elements and more clay minerals is higher than that of dark-grey mudstone. • Detailed comparison of hydrocarbon generation characteristics, molecular composition and organic petrology between mudstone and shale in the Chang 7 Member. • The difference of hydrocarbon generation potential between mudstone and shale is mainly affected by paleo-productivity and preservation environment. • The difference of hydrocarbon generation characteristics between mudstone and shale is mainly affected by macerals composition and organic matter source. [ABSTRACT FROM AUTHOR]