Surface defects engineered Bi4Ti3O12 nanosheets for photocatalytic degradation of antibiotic levofloxacin.

Surface defects have a significant effect on the photocatalytic reaction of Bi 4 Ti 3 O 12 , but the mechanism is unclear. In addition, when surface defects and highly exposed facets exist at the same time, which factor plays the main role in photocatalytic activity is also controversial. Herein, it is found that Bi 4 Ti 3 O 12 with adjustable concentrations of surface defects and percentage of exposed {001} facets can be prepared by using titania of different crystal types and sizes as raw materials, which is extremely beneficial for exploring the above problems. The photocatalytic activity of Bi 4 Ti 3 O 12 nanosheets with surface defects and exposed {001} facets was the same as that of Bi 4 Ti 3 O 12 nanosheets with surface defects alone (about 72.5% of photodegradation levofloxacin under 10 min of simulated sunlight irradiation). Based on the experimental results and density functional theory calculations, the influence mechanism of surface defects was deeply studied. The surface defects resulting from partial exfoliation of the external (Bi 2 O 2)2+ layers changed band structure of Bi 4 Ti 3 O 12. More importantly, surface defects with high concentration became hole trapping sites, which was conducive to the faster participation of holes in the photocatalytic oxidation process. [Display omitted] • Bi 4 Ti 3 O 12 with surface defects and exposed {001} facets was prepared. • The surface defects resulted from partial exfoliation of (Bi 2 O 2)2+ layers. • The enhanced photocatalytic performance was determined by the surface defects. • Surface defects with high concentration served as hole trapping sites. [ABSTRACT FROM AUTHOR]