Highly dispersed dialkyl dithiophosphate-functionalized ZIF-8 particles as additives of the lubricating oil.

Purpose: This paper aims to propose a new strategy to functionalize zeolitic imidazolate frameworks (ZIF-8) to improve its dispersion stability and tribological properties in lubricating oil. Design/methodology/approach: Dialkyl dithiophosphate polydopamine ZIF-8 (DDP@PDA@ZIF-8) was prepared via mussel-inspired chemistry and the Michael addition reaction. The tribological properties of DDP@PDA@ZIF-8 as an additive in the white oil were evaluated with four-ball friction and wear tester at different temperatures. The worn surface was analyzed using X-ray photoelectron spectrum (XPS). Findings: The as-prepared DDP@PDA@ZIF-8 shows high dispersion stability in the white oil. Tribological results confirmed that the DDP@PDA@ZIF-8 exhibited a small wear scar diameter at 25°C. However, excellent friction reduction and anti-wear properties were observed at 75°C. The XPS result indicates that a series of tribochemical reactions occurred on the worn surface, forming the complex protective film. Originality/value: This paper provides a study of highly dispersed ZIF-8 as lubrication additives. [ABSTRACT FROM AUTHOR]