Back to Search Start Over

Sn368−: a 2.7 nm naked aromatic tin rod.

Authors :
Tkachenko, Nikolay V.
Chen, Wei-Xing
Morgan, Harry W. T.
Muñoz-Castro, Alvaro
Boldyrev, Alexander I.
Sun, Zhong-Ming
Source :
Chemical Communications. 5/25/2022, Vol. 58 Issue 42, p6223-6226. 4p.
Publication Year :
2022

Abstract

In this work, we synthesize naked tin cluster anion Sn368−, representing the first example of pure Sn nanowire assembled through oxidative coupling reactions of a super atomic cluster Sn94−. Theoretical analysis confirm the presence of aromaticity for each Sn9 unit showing four adjacent aromatic subunits bridged by parallel Sn–Sn bonds. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
58
Issue :
42
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
157076668
Full Text :
https://doi.org/10.1039/d2cc01745h