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Synthesis of chitosan/SnO2 nanocomposites by chemical precipitation for enhanced visible light photocatalytic degradation efficiency of congo red and rhodamine-B dye molecules.

Authors :
Maruthupandy, Muthuchamy
Muneeswaran, Thillaichidambaram
Chackaravarthi, Gnanasekaran
Vennila, Thirumalaiswamy
Anand, Muthusamy
Cho, Wan-Seob
Quero, Franck
Source :
Journal of Photochemistry & Photobiology A: Chemistry. Sep2022, Vol. 430, pN.PAG-N.PAG. 1p.
Publication Year :
2022

Abstract

[Display omitted] • SnO 2 NPs and CS/SnO 2 NCs were synthesized by a chemical precipitation method. • TEM revealed that the nanosized SnO 2 NPs were homogeneously distributed within the CS matrix. • CS/SnO 2 NCs demonstrated enhanced photodegradation efficiency against CR and Rh-B. Tin oxide (SnO 2) nanoparticles (NPs) as well as SnO 2 /chitosan(CS) nanocomposites (NCs) were successfully synthesized by a simple chemical precipitation technique and their photocatalytic degradation ability against congo red (CR) and Rhodamine-B (Rh-B) were subsequently evaluated. The crystallinity and surface morphology of the materials were evaluated using X-ray diffraction analysis and transmission electron microscopy (TEM), respectively. The TEM images revealed that nanosized SnO 2 NPs were successfully obtained and were homogeneously distributed within the CS matrix. The CS/SnO 2 NCs were exposed to Rh-B dye molecules, resulting in 95% degradation within 60 min, which was significantly higher than for SnO 2 NPs. On the other hand, CS/SnO 2 NCs were found to degrade 98% of CR dye molecules within 40 min of visible light irradiation, which was also significantly shorter than for SnO 2 NPs. The CR dye molecules experienced significantly better levels of photodegradation parameters than Rh-B. The present study demonstrates the potential of CS/SnO 2 NCs in the area of environmental remediation of organic dye-based water pollutants. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
10106030
Volume :
430
Database :
Academic Search Index
Journal :
Journal of Photochemistry & Photobiology A: Chemistry
Publication Type :
Academic Journal
Accession number :
156942196
Full Text :
https://doi.org/10.1016/j.jphotochem.2022.113972