Back to Search
Start Over
Metarhizides A–C and metarhizosides A–B: PKS-NRPS macrolides and aromatic glycosides from an Australian fish gut-derived fungus, Metarhizium sp. CMB-F624.
- Source :
-
Tetrahedron . May2022, Vol. 113, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
-
Abstract
- Chemical and cultivation profiling of an Australian Mugil mullet gastrointestinal tract (GIT) derived fungus, Metarhizium sp. CMB-F624, prompted investigation of a scaled up rice grain cultivation leading to the discovery of three new PKS-NRPS macrolides, metarhizides A-C (1 – 3) featuring an unusual tautomerically labile α-methyl-β-keto-macrolactone, together with two new aromatic glycosides, metarhizosides A and B (4 – 5). Structures were assigned to 1 – 5 on the basis of detailed spectroscopic and chemical analysis, and biosynthetic considerations. [Display omitted] [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00404020
- Volume :
- 113
- Database :
- Academic Search Index
- Journal :
- Tetrahedron
- Publication Type :
- Academic Journal
- Accession number :
- 156627100
- Full Text :
- https://doi.org/10.1016/j.tet.2022.132759