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Two-dimensional Zr/Hf-hydroxamate metal–organic frameworks.
- Source :
-
Chemical Communications . 3/18/2022, Vol. 58 Issue 22, p3601-3604. 4p. - Publication Year :
- 2022
-
Abstract
- Novel two-dimensional kagome metal–organic frameworks with mononuclear Zr4+/Hf4+ nodes chelated by benzene-1,4-dihydroxamate linkers were synthesized. The MOFs, namely SUM-1, are chemically robust and kinetically favorable, as confirmed by theoretical and experimental studies. SUM-1(Zr) can be readily made into large (∼100 μm) single crystals and nanoplates (∼50 nm), constituting a versatile MOF platform. [ABSTRACT FROM AUTHOR]
- Subjects :
- *METAL-organic frameworks
*SINGLE crystals
*CHELATES
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 58
- Issue :
- 22
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 155868845
- Full Text :
- https://doi.org/10.1039/d2cc00213b