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Semi-infused lithium anode for advanced Li metal batteries.
- Source :
-
Electrochimica Acta . Apr2022, Vol. 410, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
-
Abstract
- • Development of lithium metal based anode through novel Semi-infusion technique. • Ni mesh to be act as a host material to accommodate li ions during stripping/plating. • The symmetrical Li/SnO 2 -Ni cell revealed a low voltage gap of ∼ 8 mV over 2000 h at 1 mA cmˉ2 and 1 mAh cmˉ2. • Full cell cycling performance of the Li/SnO 2 -Ni with LFP delivered a specific capacity of 170 mAh gˉ1 with an excellent stability. Lithium metal battery is a promising candidate for the next generation batteries due to its high theoretical specific capacity and energy density. However, the dendritic propensity of Li metal and inevitable volume variation are critical obstacles for commercialization. Here, we prepare a novel anode that Li infused partially into the tin oxide coated Ni mesh (Li/SnO 2 -Ni) by semi-infusion strategy. The strategy can provide an adequate but not excessive amount of Li in the host for the battery. The SnO 2 -Ni mesh abates the dendritic formation and volume variation due to its lithiophilic property, three-dimensional (3-D) structure, and excellent conductivity guiding the Li-ion deposition and stripping uniformly during cycling. As a result, Li/SnO 2 -Ni cell can cycle a long span with an exceptionally low voltage gap of 8, 15, and 200 mV at a different current density and of 1, 3, and 35 mA cm−2, and a capacity of 1, 1 and 5 mAh cm−2, respectively, in a symmetrical cell. The performance of full cell against LiFePO 4 cathode achieves a superior capacity of 173 mAh g−1 at 0.2 C and the retention of 90 % after 70 cycles. This work offers a facile and effective strategy to fabricate a 3-D composite anode and promotes the practical applications of Li metal batteries. [Display omitted] [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00134686
- Volume :
- 410
- Database :
- Academic Search Index
- Journal :
- Electrochimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 155862048
- Full Text :
- https://doi.org/10.1016/j.electacta.2022.139976