K/O co-doping and introduction of cyano groups in polymeric carbon nitride towards efficient simultaneous solar photocatalytic water splitting and biorefineries.

The simultaneous production of hydrogen and biomass-based chemicals from biomass-derived feedstock aqueous solutions via photocatalysis is appealing because no additional sacrificial agent is needed. However, limited success has been achieved. This paper reports efficient nori-shaped carbon nitride-based photocatalysts with potassium/oxygen co-doping and cyano group introduction for efficient conversion of biomass-derived monosaccharides to produce lactic acid and hydrogen simultaneously. The obtained photocatalyst has an adjustable bandgap, fast migration/separation rate of photo-generated carriers and displays excellent photocatalytic performance with respect to xylose conversion (∼95.0%), lactic acid selectivity (90.5%) and hydrogen generation (∼33 380 μmol g−1 h−1) in the presence of visible light. The h+, ˙OH, ˙O2− and 1O2 drive xylose conversion and lactic acid production. For biomass-derived pentoses and hexoses, the reaction system also exhibits excellent photocatalytic activity of lactic acid selectivity and hydrogen generation; the reported photocatalyst has excellent reusability. This paper provides a new perspective for hydrogen generation and biorefineries via a photocatalyst. [ABSTRACT FROM AUTHOR]