[{TcI(NO)(LOMe)(PPh3)Cl}2Ag](PF6) and [TcII(NO)(LOMe)(PPh3)Cl](PF6): Two Unusual Technetium Complexes with a "Kläui‐type" Ligand.

The reaction of [TcI(NO)(LOMe)(PPh3)Cl] ({LOMe}−=η5‐cyclopentadienyltris(dimethyl phosphito‐P)cobaltate(III)) with Ag(PF6) gives two unexpected products: the dimeric technetium(I) complex [{Tc(NO)(LOMe)(PPh3)Cl}2Ag](PF6) with a central Ag+ ion and the cationic Tc(II) compound [Tc(NO)(LOMe)(PPh3)Cl](PF6). The products have been studied spectroscopically and by X‐ray diffraction. [ABSTRACT FROM AUTHOR]