A luminescence europium Metal-organic coordination polymer for Room-Temperature X-ray detection.

A novel Eu3+ ions-based metal–organic coordination polymer with a peculiar "snake-shaped" chain structure has been synthesized, which exhibits efficient light emission, excellent line response to X-rays and high structure and luminescence stability against continuous irradiation. [Display omitted] • A new type of luminescent Eu-MOCP was synthesized by simple solvothermal method. • Synthesized Eu-based MOCP shows an efficient and stable light emission under X-ray excitation, and delivers an excellent linear response to X-ray dose. • Compound 1 demonstrates high structure and luminescence stability against continuous X-ray irradiation. In this paper, a novel Eu ions-based metal–organic coordination polymer (MOCP) named Eu(1,3,6,8-PTS)(H 2 O) 7 ·4H 2 OHbipy (1) (PTS = pyrenetetrasulfonic acid) has been prepared, and its structure, stability, photoluminescence and scintillation properties were systematically investigated. Compound 1 gives a peculiar "snake-shaped" chain structure with the aid of π-π stacking effect of 4,4′-bipyridine auxiliary template. An efficient and stable light emission was detected under X-ray irradiation, which presents an excellent linear response to X-ray dose. Moreover, this compound demonstrates high radiation stability, illustrating its potential as a scintillator for X-ray detection. This work not only provides guidance for the design and fabrication of sulfonic ligand derived MOCPs with Eu (III) ions coordiantion, but also demonstrates the potential of MOCPs scintillators for X-ray detection technology. [ABSTRACT FROM AUTHOR]