Durable and highly selective ion transport of a sulfonated Diels Alder Poly(phenylene) for vanadium redox flow batteries.

To improve the durability and ion selectivity of a hydrocarbon membrane for vanadium redox flow batteries (VRFBs) a polymer was rationally designed with an external hydrophobic shell and internal hydrophilic core. The polymer was designed to prevent hydrophilic polymer chain aggregation by functionalizing the external polymer shell with hydrophobic side chains and attaching acid moieties onto the polymer backbone. The hydrophobic shell is the result of pentafluorobenzoyl functionalization on the pendent aryl rings in a Diels Alder poly(phenylene) backbone. The internal polymer chain contains sulfonic acid moieties to impart hydrophilic character. The physical and electrochemical characteristics of the membrane were systematically studied and compared with widely used Nafion-212. The synthesized membranes were found to be superior to Nafion-212 not only in terms of lower vanadium ion permeability (4.25 × 10−8 vs. Nafion-212: 6.0 × 10−6 cm2 min −1) but also higher VRFB performance (EE = 89% and vs. Nafion-212: 85.5% at 40 mA/cm2). The membrane showed over three times higher capacity retention than Nafion-212 (0.075% vs. 0.25% capacity loss per cycle respectively) and excellent ex situ and in situ chemical stability. • Unique polymer design of an external hydrophobic shell and internal hydrophilic core. •50x higher proton/vanadium transport selectivity relative to Nafion-212. •Durable in 1.5 M VO 2 + for 60 days and 800 cycles in vanadium flow battery testing. [ABSTRACT FROM AUTHOR]