Inside Cover: Reactivities of Interstitial Hydrides in a Cu11 Template: En Route to Bimetallic Clusters (Angew. Chem. Int. Ed. 2/2022).

Keywords: cluster compounds; copper; gold; neutron diffraction; silver EN cluster compounds copper gold neutron diffraction silver 1 1 1 01/06/22 20220110 NES 220110 B Depending on the nature of M SP + sp b , the hydrides of the H SB 2 sb Cu SB 11 sb reactant behave differently. Cluster compounds, copper, gold, neutron diffraction, silver In the case of M=Cu or Ag, they act as regular two-electron ligands yielding [CuH SB 2 sb Cu SB 11 sb {S SB 2 sb P(O SP I i i sp Pr) SB 2 sb } SB 6 sb (C CPh) SB 3 sb ] SP + sp (Cu SB 12 sb H SB 2 sb ) or [AgH SB 2 sb Cu SB 14 sb {S SB 2 sb P(O SP I i i sp Pr) SB 2 sb } SB 6 sb (C CPh) SB 6 sb ] SP + sp (AgH SB 2 sb Cu SB 14 sb ); in the case of M=Au, they behave as electron donors to form [AuCu SB 11 sb {S SB 2 sb P(O SP I i i sp Pr) SB 2 sb } SB 6 sb (C CPh) SB 3 sb Cl] (AuCu SB 11 sb ). [Extracted from the article]