Enhanced photocatalytic efficiency by direct photoexcited electron transfer from pollutants adsorbed on the surface valence band of BiOBr modified with graphitized C.

Herein, a novel BiOBr photocatalyst with partial surface modification by graphitized C (BiOBr-C g) was synthesized through a hydrothermal method with hydrothermal carbonation carbon (HTCC) as a slow-releasing carbon source and characterized by experimental and theoretical methods. BiOBr-C g exhibited excellent visible-light photocatalytic performance toward various refractory pollutants, such as bisphenol A, ibuprofen, ciprofloxacin, 2,4-dichlorophenoxyacetic acid, and diphenhydramine. The characterization results demonstrate that a strong molecular orbital interaction occurs between graphitized C and BiOBr, resulting in the formation of a new surface valence band on graphitized C. This not only promotes the oxidation of pollutants by surface holes but also reduces the recombination of carriers during the bulk phase transfer process, thereby increasing the number of photogenerated carriers. Intriguingly, the analytical results for degradation intermediates and other characterization techniques demonstrate that the pollutants adsorbed on the graphitized C of BiOBr-C g can be directly excited through light irradiation and react along the organic radical degradation pathway in addition to pollutant degradation by holes and HO 2 •/O 2 •-. [Display omitted] • A novel BiOBr photocatalyst (BiOBr-C g) partly coated by graphitized C with HTCC as a slow-releasing carbon source. • The surface valence band derived from graphitized C reduces the recombination of e-/h+ during bulk phase transfer process. • The pollutant adsorbed on BiOBr-C g promotes direct transfer of excited electrons along organic radical degradation pathway. • Pollutant adsorption plays a role of molecular modification to facilitate the generation of more HO 2 •/O 2 •-. [ABSTRACT FROM AUTHOR]