Preparation of PAMAM modified PVDF membrane and its adsorption performance for copper ions.

As one of the main pollutants of water pollution, the potential toxicity of heavy metal ions always threatens the safety of human and nature. Therefore, how to effectively remove heavy metal ions has become an important research topic in environmental protection. In the existing research, adsorption method is outstanding from many methods because of its high adsorption efficiency and easy operation. In this study, different generations of hyperbranched polyamide-amine (PAMAM) were grafted onto PVDF membrane to obtain the membrane with high adsorption capacity for heavy metal ions. The structure and physicochemical properties of the membranes were evaluated by means of fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (FE-SEM), element analyzer and X-ray photoelectron spectroscopy (EDX). At the same time, various factors affecting the adsorption process were studied, and it was found that the adsorption behavior of copper ion (Cu2+) on the membrane conformed to the pseudo-first-order kinetic model and Langmuir isotherm model. Moreover, after comparing the adsorption effect of the modified membranes grafted with different generations of PAMAM, it was found that the membrane grafted with the third generation PAMAM had the best adsorption when the solution pH was 5, and its maximum adsorption capacity could reach 153.8 mg/g. After five adsorption-desorption cycles, its adsorption capacity can reach 72.83% of the first test, indicating that it has good recycling performance. The results show that the adsorption membrane has good application potential and research value. [Display omitted] • The adsorption capacity of PVDF-g-PAMAM membrane for copper ions reached 153.8 mg/g. • The modified membranes grafted with the third generation PAMAM have the higher adsorption capacity than other modified membranes. • The steric hindrance effect and the number of amino groups have important effects on the adsorption capacity of the modified membranes. [ABSTRACT FROM AUTHOR]