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Optical Properties in Heteronuclear Gold(I)/Silver(I) Complexes of Aliphatic Mixed‐Donor Macrocycles Featuring Metallophilic Interactions.
- Source :
-
European Journal of Inorganic Chemistry . 11/25/2021, Vol. 2021 Issue 44, p4552-4559. 8p. - Publication Year :
- 2021
-
Abstract
- The reaction of the polymeric heterometallic compound [{Au(C6Cl5)2}Ag]n with the macrocyclic ligands 1‐aza‐4,7,10‐trithiacyclododecane (L1), 1,7‐diaza‐4,11‐dithiacyclododecane (L2), 1‐aza‐4,10‐dithia‐7‐oxacyclododecane (L3) in tetrahydrofuran (THF) and 1 : 1 reaction molar ratio affords the new Au(I)/Ag(I) complexes [{Au(C6Cl5)2}{Ag(L1)}] (1), [{Au(C6Cl5)2}{Ag(L2)}] (2), [{Au(C6Cl5)2}{Ag(L3)}] (3) and [{Au(C6Cl5)2}{Ag(L3)}]2 (4) that have been structurally characterized. Despite 1–3 show the same nature of binuclear complexes, only 3 changes its luminescence properties upon grinding as a consequence of partial amorphization. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14341948
- Volume :
- 2021
- Issue :
- 44
- Database :
- Academic Search Index
- Journal :
- European Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 153791436
- Full Text :
- https://doi.org/10.1002/ejic.202100618