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Crystal Structure of the Molecular Complex of Silicon Tetrafluoride with 4-Phenylpyridine.
- Source :
-
Russian Journal of General Chemistry . Oct2021, Vol. 91 Issue 10, p1964-1968. 5p. - Publication Year :
- 2021
-
Abstract
- The crystal structure of the silicon tetrafluoride molecular complex with 4-phenylpyridine SiF4·2ppy has been determined by X-ray diffraction analysis. Although 4-phenylpyridine has a higher proton affinity than pyridine, the Si–N bond length in crystalline SiF4·2Py is shorter by 0.03(2) Å than in SiF4·2ppy. The energies of donor-acceptor Si–N bonds in SiF4·2Py (220.6 kJ/mol) and SiF4·2ppy (225.0 kJ/mol) calculated by the M06-2X/def2-TZVP method agree with a slightly higher proton affinity of 4-phenylpyridine. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10703632
- Volume :
- 91
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Russian Journal of General Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 153455467
- Full Text :
- https://doi.org/10.1134/S1070363221100066