Geochemical and mineralogical evidence of an offset in the Andean arc recorded in the Upper Cretaceous marine deposits of the Austral-Magallanes basin, Argentina.

The Austral-Magallanes Basin covers the southernmost region of Patagonia, South America. South of Lago Argentino, the Calafate Formation documents part of the foreland stage of the evolution of this basin. Here, sandstones from the Calafate Formation were characterized using petrographical, X-ray diffraction (XRD) and geochemical data in order to establish their tectonic setting and sediment source areas. Based on our results, three intervals (lower, middle, and upper) were distinguished according to their composition. The lower and upper intervals are composed of felsic volcanic lithics, abundant quartz and orthoclase. A shift in the composition was observed in the middle interval, with an increase in the modal abundance of plagioclase as well as other accessory minerals such as pyroxene. In addition, XRD data reveal that the middle interval is dominated by smectite in the clay-fraction, whereas the lower and upper intervals present mixed-layer chlorite-smectite and chlorite assemblages. Similar differences are observed using major and trace elements: data from the lower and upper intervals point to source rocks of intermediate to acid composition, while the middle interval had source rocks of intermediate composition and a lower degree of weathering. With regard to the provenance studies, the three intervals have a strong affinity to intermediate compositions of the Tobífera Formation (El Quemado Complex) and with the diorite/andesite of the Patagonian Batholith, which implies an exclusive contribution from the western edge of the basin. However, the shift in the composition towards the middle interval indicates a sediment supply from the juvenile Andean arc, suggesting contemporaneous magmatic activity during the deposition of the Calafate Formation sandstones. This peak of magmatic activity may have been caused by an eastward migration of the arc, driven by a switch in the tectonic setting south of 48°S. • Petrographic and XRD analyses show changing compositional signatures throughout the unit. • Al 2 O 3 -(Na 2 O+CaO)–K 2 O diagram and CIA values indicate initial-moderately weathered sources. • Samples have Zr/Sc ratios of ~3 meaning that they are depleted compared to typical UCC. • In the Th/Sc–Zr/Sc and Co/Th–La/Sc diagram samples plot between the andesitic and granitic field. • Nb <20ppm and Zr <350ppm values indicate a tectonic affinity of a subduction-related volcanic arc. [ABSTRACT FROM AUTHOR]