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Binary CuO/TiO2 nanocomposites as high-performance catalysts for tandem hydrogenation of nitroaromatics.
- Source :
-
Colloids & Surfaces A: Physicochemical & Engineering Aspects . Nov2021, Vol. 629, pN.PAG-N.PAG. 1p. - Publication Year :
- 2021
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Abstract
- In situ hydrogenation of unsaturated compounds by released hydrogen from various hydrogen sources is a good strategy to achieve highly selective hydrogenation. In this work, inexpensive CuO/TiO 2 nanocomposites were systematically screened their performance for catalyzing dehydrogenation of ammonia borane (AB) and the tandem hydrogenation of some nitroaromatics. Those CuO/TiO 2 binary nanocomposites were found to maximize the hydrogen production from the catalytic hydrolysis of AB. Owing to a positive in-situ hydrogen activation, under mild conditions these CuO/TiO 2 nanocomposites exhibited highly excellent reactivities accompanying with better recyclability in the current one-pot hydrogenation. Notably, a selected CuO (0.5) /TiO 2(0.5) nanocomposites displayed high activity and regioselectivity (up to100% yield of aim product) as well as increased ability of inhibiting the dehalogenation reaction, especially for 4-bromonitrobenzene or 4-iodonitrobenzene (up to 71.65% yield for 4-bromoaniline or 68.02% yield of 4-iodoaniline). Moreover, that CuO (0.5) /TiO 2(0.5) nanocomposites from a co-precipitation method displayed relatively better recyclability against those two control samples obtained from a stepwise preparation process. Owing to positive in-situ hydrogen activation mechanism, CuO/TiO 2 binary nanocomposites from co-precipitation method display highly excellent reactivity, regioselectivity, and better recyclability for the tandem hydrogenation of aromatic nitro-compounds under highly mild conditions. [Display omitted] • Binary CuO/TiO2 nanocomposites exhibited attractive reactivity toward the tandem hydrogenation of nitro-compounds. • Control experiments powerfully confirm a positive in-situ hydrogen activation benefitting the efficient tandem hydrogenation. • Distinguishable catalytic performances were observed for those catalysts coming from different preparation methods. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09277757
- Volume :
- 629
- Database :
- Academic Search Index
- Journal :
- Colloids & Surfaces A: Physicochemical & Engineering Aspects
- Publication Type :
- Academic Journal
- Accession number :
- 152921248
- Full Text :
- https://doi.org/10.1016/j.colsurfa.2021.127383