Active copper species of co-precipitated copper-ceria catalysts in the CO-PROX reaction: An in situ XANES and DRIFTS study.

[Display omitted] • DRIFTS and XANES analyses shed light on the active Cu species in the PROX. • The oxidation state of Cu catalysts depends on the temperature and Cu content. • A drastic decrease in CO conversion is related to oxidation of Cu species to Cu2+. • Cu+ and Cu0 are active species in co-precipitated catalysts in the PROX reaction. • A PROX mechanism on CuCe catalysts involving Cu0/Cu+ and Ce3+/Ce4+ was proposed. Properties of co-precipitated CuO/CeO 2 catalysts with nominal content of 1–3 wt.% copper were investigated by EDS, XRD, BET, STEM, EDS map, H 2 -TPR, in situ DRIFTS and in situ XANES. By comparing results of DRIFTS, XANES and catalytic performance in the CO-PROX reaction, it was evidenced a relationship between the catalytic behavior and the copper oxidation state of the materials. In situ DRIFTS and XANES analyses shed light on the oxidation state of active copper species involved in the CO-PROX reaction between 120 °C and 200 °C. The investigated catalysts present a balance between Cu° and Cu+ species under PROX conditions and the Cu+ is the main species liable to adsorb CO. Furthermore, our studies indicated that the PROX reaction on CuO/CeO 2 is impacted by the nature of Cu species, which in turn may vary with reaction temperature, depending on the Cu content. From these results, we propose a new mechanism of PROX reaction on CuCe catalysts, including Cu°/Cu+ and Ce3+/Ce4+ redox pairs and direct CO oxidation on Cu°. [ABSTRACT FROM AUTHOR]