The thermophysical properties and the molten CMAS resistance performance of Ytterbium Tantalate.

The development of YSZ TBCs has been limited by the CMAS corrosion and thermophysical characteristics. The Ytterbium Tantalate (YbTaO 4) ceramic was selected in this study to evaluate its potential to replace traditional YSZ. The thermal and mechanical properties of YbTaO 4 show great advantages over YSZ, especially the hardness (191.3 ± 7.6 Hv 0.3). The CMAS hot corrosion results indicate that the maximum thickness of the reaction layer at 1350 °C after 24 h is ~16.8 μm, which is much thinner than that of YSZ. Moreover, the porosity of the reaction layer does not increase significantly compared with the YSZ TBCs. The main product after the reaction is the Ca 2 Ta 2 O 7 phase, and there is no anorthite phase after the reaction, mainly because the formation of the Ca 2 Ta 2 O 7 phase consumes a lot of Ca atoms. In addition, the equilibrium contact angle of YbTaO 4 is higher than that of YSZ, which indicates that the YbTaO 4 possesses worse wettability. In actual conditions, low wettability is conducive to the YbTaO 4 TBCs get rid of the liquid CMAS, which can effectively reduce the corrosion effect of CMAS. Furthermore, the corrosion depth and area of YbTaO 4 causing by residual CMAS are also smaller due to the poor wettability. Based on the above results, YbTaO 4 exhibits excellent potential to replace YSZ in preparing TBCs for the next generation aero engines. • The on-line contact angle was measured by the high-temperature contact angle analyzer. • The CMAS glass on the YbTaO 4 samples has not disappeared after different time reaction. • The reaction layer thickness of YbTaO 4 after 24 h CMAS attacking is thinner than YSZ TBCs. • The YbTaO 4 ceramics possess worse CMAS wettability compared with the YSZ. [ABSTRACT FROM AUTHOR]