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Sodium Sulfide in the Synthesis of N-Alkyl-1,3,5-dithiazinanes and 1,3,5-Thiadiazinanes.

Authors :
Khabibullina, G. R.
Yapparova, D. K.
Ibragimov, A. G.
Akhmetova, V. R.
Source :
Russian Journal of General Chemistry. Aug2021, Vol. 91 Issue 8, p1453-1458. 6p.
Publication Year :
2021

Abstract

An approach to the synthesis of 1,3,5-dithiazinanes and 1,3,5-thiadiazinanes was developed based on the cyclothiomethylation of aliphatic amines with 9-aqueous Na2S and CH2O. Linear aliphatic primary amines form predominantly 1,3,5-thiadiazinanes, while branched ones lead to the formation of 1,3,5-dithiazinanes. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
10703632
Volume :
91
Issue :
8
Database :
Academic Search Index
Journal :
Russian Journal of General Chemistry
Publication Type :
Academic Journal
Accession number :
152318683
Full Text :
https://doi.org/10.1134/S1070363221080053