CO2 and N2 adsorption/desorption effects and thermodynamic characteristics in confined coal.

Gas injection into coal seams is gaining increasing attention for improving coalbed methane (CBM) production. This technical development requires detailed and reliable information on gas adsorption/desorption-induced deformation and gas occurrence mechanisms. Hence, in this paper, high volatile bituminous coal was taken as the experiment samples from northern Shannxi Province, China, and adsorption-induced swelling experiments with CO 2 and N 2 were carried out under the conditions of one-time injection and step-by-step injection. Then, based on adsorption-induced swelling characteristics, a thermodynamic model was further established to disclose the adsorption/desorption-induced deformation mechanism of confined coals. Results showed that the swelling/shrinkage strain curves of CO 2 and N 2 adsorption/desorption in the coal matrix were generally divided into four stages, including pressurization-deformation, adsorption-induced swelling, depressurization-deformation, and finally desorption-induced shrinkage. It can be seen that the coal swelling effect caused by N 2 adsorption was far less than that caused by CO 2 adsorption. However, both CO 2 and N 2 adsorption displayed that the apparent volumetric swelling weakened with increasing strain when compared with the same adsorption pressure under different strain conditions. In contrast, the absolute volumetric swelling of the confined coal was a coupling result from adsorption-induced swelling and pore pressure effects. Further, based on the thermodynamic model, it was verified that the adsorbate type, the chemical potential of the adsorbate molecule and stress conditions are key factors affecting adsorption-induced swelling of coal under a certain temperature and pressure. In addition, a desorption lag phenomenon during the desorption-induced shrinkage stage was observed, due to incomplete gas desorption and gas retention in the coal macromolecular network. It was also found that there was a shrinkage phenomenon after the peak strain during gas adsorption. That is to say, when fixed adsorption sites on the coal pore surface reached the adsorption saturation state at the peak strain, gas molecules would be stored in an absorption state in the coal macromolecular network under continuous adsorption. These phenomena further explained coal swelling and gas occurrence mechanisms. • Swelling/shrinkage strain curve can be generally divided into four stages. • Absolute volumetric swelling is controlled by adsorption swelling and pore pressure. • Thermodynamic model reflects Gibbs free energy of gas adsorption in coal decreases. • Adsorption-induced swelling effect tends to be dropped with increasing stress. • Shrinkage effect after peak strain and desorption lag are occurred in whole process. [ABSTRACT FROM AUTHOR]