Fabrication and thermal shock behavior of ZrO2 toughened magnesia aggregates.

MgO-based refractories have been regarded as ideal linings for various furnaces owing to high refractoriness and excellent corrosion resistance to basic slag. However, thermal shock damage resulting from poor thermal shock resistance (TSR) of magnesia is the common failing. The present work aimed at improving TSR of magnesia aggregates by introducing microscale monoclinic ZrO 2. The results showed that the ZrO 2 added could increase cation vacancy concentration and inhibit abnormal growth of MgO grains, which therefore enhanced densification of the specimens. However, when the ZrO 2 amount exceeded 15 wt%, densification decreased slightly due to agglomeration of ZrO 2 and formation of more microcracks at the MgO grain boundaries. With increasing ZrO 2 content, although the flexural strength degraded, the fracture toughness increased constantly because of the toughening effects of crack deflection and crack branching. Besides, although the addition of ZrO 2 decreased the thermal conductivity, TSR of the specimens was significantly improved with increasing ZrO 2 content due to the increase in toughness and decrease in strength, thermal expansion coefficient as well as Young's modulus. After thermal shock tests, 15 wt% ZrO 2 containing specimen exhibited the highest TSR, whose residual strength ratio was about triple of that of the pure magnesia specimen. However, further increasing ZrO 2 content to 20 wt% reduced the TSR attributing to the spalling of intergranular ZrO 2 agglomerations. [ABSTRACT FROM AUTHOR]