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A matryoshka-like CuS@void@Co3O4 double microcube-locked sulfur as cathode for high-performance lithium-sulfur batteries.
- Source :
-
Ceramics International . Sep2021, Vol. 47 Issue 18, p25769-25776. 8p. - Publication Year :
- 2021
-
Abstract
- Lithium-sulfur battery cathodes still remain a challenge on capacity decay due to the shuttle effect even though a series of strategies have been tried. Here we report a novel matryoshka-like CuS@void@Co 3 O 4 architecture of double micro-cubes (μ -cubes) that locks sulfur between the CuS core and the Co 3 O 4 shell. Plenty of existing spaces between the μ -cubes suffice a high loading of sulfur and volumetric accommodation. The robust, double closed cubes configuration greatly enhances the confinement of polysulfides. In parallel, the CuS core increases the electronic conductivity and contributes to additional capacity, while the Co 3 O 4 shell ensures a better interface activity. A high Li+ ion diffusion coefficient is obtained during the sulfur and lithium sulfide transformation. The constructed battery displays an initial capacity up to 1480 mAh g−1, and a Coulombic efficiency (CE) exceeding 99%. A capacity retention higher than 500 mAh g−1 with a CE larger than 99.8% after cycling 400 times at 0.2 C are achieved. In addition, under a temperature of −5 °C, a high capacity of 700 mAh g−1 at 0.2 C after 200 cycles is achieved, indicating a good low-temperature tolerance. [ABSTRACT FROM AUTHOR]
- Subjects :
- *LITHIUM sulfur batteries
*SULFUR
*CATHODES
*DIFFUSION coefficients
*POLYSULFIDES
Subjects
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 47
- Issue :
- 18
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 151646853
- Full Text :
- https://doi.org/10.1016/j.ceramint.2021.05.304