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Ni-B catalyst with metal modifiers for partial hydrogenation of fatty acid methyl esters at mild conditions.
- Source :
-
Journal of Chemical Sciences . Sep2021, Vol. 133 Issue 3, p1-12. 12p. - Publication Year :
- 2021
-
Abstract
- A low-cost Ni-B alloy catalyst was prepared by chemical reduction method and used for partial hydrogenation of fatty acid methyl esters. The conditions for catalyst preparation, including Ni to B ratio, pH of NaBH4 solution, types and quantity of metal modifiers were optimized. Ni-La-B, prepared by modification of Ni-B with La, showed significantly high catalytic partial hydrogenation activity. The optimum textural properties (small particle size, high specific surface area and well-defined pore structure) and electron enrichment of active Ni sites were the favorable factors for the high hydrogenation activity of Ni-La-B catalyst, which showed reasonable stability in catalyst recycle experiments. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09743626
- Volume :
- 133
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Journal of Chemical Sciences
- Publication Type :
- Academic Journal
- Accession number :
- 151541293
- Full Text :
- https://doi.org/10.1007/s12039-021-01930-5