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Boron‐ versus Nitrogen‐Centered Nucleophilic Reactivity of (Cyano)hydroboryl Anions: Synthesis of Cyano(hydro)organoboranes and 2‐Aza‐1,4‐diborabutatrienes.
- Source :
-
Chemistry - A European Journal . 7/2/2021, Vol. 27 Issue 37, p9694-9699. 6p. - Publication Year :
- 2021
-
Abstract
- Cyclic alkyl(amino)carbene‐stabilized (cyano)hydroboryl anions were synthesized by deprotonation of (cyano)dihydroborane precursors. While they display boron‐centered nucleophilic reactivity towards organohalides, generating fully unsymmetrically substituted cyano(hydro)organoboranes, they show cyano‐nitrogen‐centered nucleophilic reactivity towards haloboranes, resulting in the formation of hitherto unknown linear 2‐aza‐1,4‐diborabutatrienes. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ANIONS
*PROTON transfer reactions
Subjects
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 27
- Issue :
- 37
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 151211901
- Full Text :
- https://doi.org/10.1002/chem.202101025