Highly Efficient Electrofluorescence Material Based on Pure Organic Phosphor Sensitization**.

Pure organic room‐temperature phosphorescence (RTP) materials are considered as potential candidates for replacing precious metal complexes to fabricate highly efficient organic light‐emitting devices (OLEDs). However, applications of the reported RTP materials in OLEDs are seriously impeded by their low photoluminescence quantum yields (PLQYs) in a thin film state. To overcome these obstacles, we established a new strategy to construct highly efficient OLEDs based on a pure organic RTP material sensitized fluorescence emitter by selecting benzimidazole‐triazine molecules (PIM‐TRZ), 2,6‐di(phenothiazinyl)naphthalene (β‐DPTZN), and 5,6,11,12‐tetraphenylnaphthacene (rubrene) as host, phosphor sensitizer, and fluorescent emitter, respectively. The perfect combination of host, phosphorescent sensitizer, and fluorescent emitter in the emitting layer ensure the outstanding performance of the devices with an external quantum efficiency (EQE) of 15.7 %. [ABSTRACT FROM AUTHOR]