Nanowire-structured FeP-CoP arrays as highly active and stable bifunctional electrocatalyst synergistically promoting high-current overall water splitting.

[Display omitted] • Fe 0.14 Co 0.86 -P/CC is fabricated by hydrothermal plus phosphating treatment. • The catalyst exhibits excellent HER/OER performance in alkaline solution. • The bifunctional catalyst only needs 1.95/2.14 V to reach 500/1000 mA cm−2. • The synergy between FeP and CoP species dominates the excellent performance. The design and construction of highly efficient and durable non-noble metal bifunctional catalysts for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in alkaline media is essential for developing the hydrogen economy. To achieve this goal, we have developed a bifunctional nanowire-structured FeP-CoP array catalyst on carbon cloth with uniform distribution through in-situ hydrothermal growth and phosphating treatment. The unique nanowire array structure and the strong electronic interaction between FeP and CoP species have been confirmed. Electrochemical studies have found that the designed Fe 0.14 Co 0.86 -P/CC catalyst appears excellent HER (130 mV@10 mA cm−2)/OER (270 mV@10 mA cm−2) activity and stability. Moreover, the bifunctional Fe 0.14 Co 0.86 -P/CC(+/−) catalyst is also used in simulated industrial water splitting system, where the pair catalyst requires about 1.95 and 2.14 V to reach 500 and 1000 mA cm−2, even superior to the control RuO 2 (+)||Pt/C(−) catalyst, showing good industrial application prospects. These excellent electrocatalytic properties are attributed to the synergy between FeP and CoP species as well as the unique microstructure, which can accelerate charge transfer, expose more active sites and enhance electrolyte diffusion and gas emissions. [ABSTRACT FROM AUTHOR]