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Mn(III)-mediated cascade cyclization of 1-(azidomethyl)-2-isocyanoarenes with organoboronic acids: construction of quinazoline derivatives.
- Source :
-
New Journal of Chemistry . 6/14/2021, Vol. 45 Issue 22, p9811-9817. 7p. - Publication Year :
- 2021
-
Abstract
- A novel and efficient Mn(III)-mediated oxidative radical cascade reaction of 1-(azidomethyl)-2-isocyanoarenes with organoboronic acids is reported. The single electron oxidation of a commercially available organo boronic acid in the presence of a mild oxidant, Mn(OAc)3·2H2O, resulted in moderate yields of the corresponding quinazoline derivatives. [ABSTRACT FROM AUTHOR]
- Subjects :
- *QUINAZOLINE
*RING formation (Chemistry)
*BORONIC acids
*ACIDS
*OXIDIZING agents
Subjects
Details
- Language :
- English
- ISSN :
- 11440546
- Volume :
- 45
- Issue :
- 22
- Database :
- Academic Search Index
- Journal :
- New Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 150744902
- Full Text :
- https://doi.org/10.1039/d1nj01115d