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Harnessing oxygen vacancy in V2O5 as high performing aqueous zinc-ion battery cathode.
- Source :
-
Journal of Alloys & Compounds . Jul2021, Vol. 870, pN.PAG-N.PAG. 1p. - Publication Year :
- 2021
-
Abstract
- • In the present work, oxygen vacancies are introduced into V 2 O 5 lattice for high performing aqueous zinc-ion battery. • The battery reaches an ultra-long cyclic duration of 620 h at 0.2 A g−1 without any significant capacity fading. • The oxygen-deficient V 2 O 5 possesses significantly higher specific capacity and better cyclic stability than pristine V 2 O 5. [Display omitted] Rechargeable aqueous zinc-ion batteries (ZIBs) have attracted considerable attention for large-scale energy storage systems due to their high energy density, low cost, and inherent safety. However, ZIBs suffer from limited cyclic stability with the use of the current cathode materials (such as V 2 O 5) due to the strong electrostatic ion–lattice interactions with the diffusing divalent Zn2+, usually leading to a limited cyclic duration (<400 h). Herein, oxygen vacancies are introduced into V 2 O 5 lattice to promote Zn2+ diffusion kinetic, thus enhancing the storage capacity and Zn2+ (de)intercalation processes, so as to high reversibility. In this work, the oxygen-deficient V 2 O 5 displays improvements in electrochemical performances over the pristine V 2 O 5. The as-assembled Zn//oxygen-deficient V 2 O 5 battery shows an impressive stability of 90% capacity retention over 1000 cycles as compared to Zn//pristine V 2 O 5 with 59% capacity retention over 680 cycles at a current density of 2 A g−1. It is also able to attain a high reversible specific capacity of approximately 406 mAh g−1 at 0.1 A g−1, which is 33% higher as compared to the capacity of pristine V 2 O 5 (307 mAh g−1). More importantly, the Zn//oxygen-deficient V 2 O 5 battery reaches an ultra-long cyclic duration of 620 h at 0.2 A g−1 without any significant capacity fading, which is, to the best of our knowledge, one of the best cyclic performance reported for V 2 O 5 system. Thus, based on these encouraging results, harnessing oxygen vacancies in V 2 O 5 may help to further enhance the electrochemical performance of the cathodes towards high performing ZIBs. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 870
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 149838045
- Full Text :
- https://doi.org/10.1016/j.jallcom.2021.159403