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Pitch-derived carbon quantum dots as fluorescent probe for selective and sensitive detection of ferric ions and bioimaging.
- Source :
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Journal of Photochemistry & Photobiology A: Chemistry . May2021, Vol. 412, pN.PAG-N.PAG. 1p. - Publication Year :
- 2021
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Abstract
- [Display omitted] • CQDs were synthesized via coal tar pitch with ozone oxidation method. • The method provides advantages of low-cost, convenience, and environmentally attractive. • CQDs showed a highly sensitivity and selectivity in detection of Fe3+ ions. • CQDs can be used in fluorescence imaging of cells. Carbon quantum dots (CQDs) emerging as newcomers of carbon nanoparticles exhibit fascinating electro-optical properties, and thereby have been widely used in many fields. Herein, we present a new facile, economical and environmentally attractive strategy for the preparation of CQDs via one-step ozone (O 3) treatment of coal tar pitch (CTP). CQDs prepared by this approach exhibit a narrow size distribution between 3–7 nm, and CQDs with a diameter of 4.8 nm accounts for approximately 42.8 %. CQDs were investigated as fluorescent probes for the detection of metal ions, and demonstrated highly sensitive and selective detection of Fe3+ ions. A calibration curve displayed a linear response over the range of 0–9 μM and a detection limit of 0.02 μM (1.12 ppb). Moreover, the photoluminescence performance of the CQDs/Fe3+ complex could be recovered with the addition of EDTA, indicating a great potential for applications of this unique fluorescent CQDs in the detection of Fe3+. Finally, the experiments of CQDs in cell imaging confirmed that the CQDs can be used as potential fluorescent probes in biological imaging, cell labeling with strong luminescence and low toxicity. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10106030
- Volume :
- 412
- Database :
- Academic Search Index
- Journal :
- Journal of Photochemistry & Photobiology A: Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 149615051
- Full Text :
- https://doi.org/10.1016/j.jphotochem.2021.113253