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Computational Study of the Hydrogenation Sequence of the Phosphorous Atom on Interstellar Dust Grains.

Authors :
Molpeceres, Germán
Kästner, Johannes
Source :
Astrophysical Journal. 3/20/2021, Vol. 910 Issue 1, p1-8. 8p.
Publication Year :
2021

Abstract

The detection of phosphorous-bearing molecules in interstellar environments constitutes a fundamental task for understanding the formation of prebiotic molecules, but it is also a challenge. In cold interstellar environments, where rich chemistry is expected to happen, only PN and PO have been detected. Phosphine (PH3) must also play an essential role in these regions, since P is expected to deplete onto dust grains significantly, and hydrogenation reactions are dominant in such environments. Surface chemistry on dust grains shows a particular idiosyncrasy where an equilibrium between competitive reactions, photoconversion processes, and desorption are in continuous interplay, modifying both the dust composition and the gas composition. In this study, we theoretically study in detail the interconversion of P to PH3 via subsequent additions of H on cold dust grain analogs. For all reactions, we provide the binding energy of the adsorbates, reaction energies, and, when present, activation barriers and tunneling-corrected rate constants. We also present an estimate of the desorption temperature of these species based on transition state theory. Using recently available experimental results on PH3 desorption via chemical reactions, we conclude that all of the intermediate products of the hydrogenation sequence to phosphine may be released to the gas phase. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
0004637X
Volume :
910
Issue :
1
Database :
Academic Search Index
Journal :
Astrophysical Journal
Publication Type :
Academic Journal
Accession number :
149590204
Full Text :
https://doi.org/10.3847/1538-4357/abe38c