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Sulfur and nitrogen co-doped carbon nanosheets for improved sodium ion storage.
- Source :
-
Journal of Alloys & Compounds . Jul2021, Vol. 868, pN.PAG-N.PAG. 1p. - Publication Year :
- 2021
-
Abstract
- • S, N co-doped carbon nanosheets are prepared as SIBs anode. • S, N co-doping endows enlarged interlamellar spacing and defective active sites for improved sodium storage. • S, N co-doping improves Na+ diffusion coefficient. • High capacity of 270 mAh g−1 is obtained at 0.1 A g−1 after 100 cycles. • Capacity of 100 mAh g−1 is achieved at high rate of 1 A g−1 after long-term 1000 cycles. Heteroatom doping into specific nanostructure is believed as the leading solution for developing the advanced carbon materials for sodium ion batteries (SIBs), however, the preparation and understanding of heteroatoms co-doped carbon anodes are still challenging. Herein, the sulfur and nitrogen co-doped (weight content of 15.64% for N and 3.1% for S) carbon nanosheets (SNC) are prepared by treating nitrogen-rich carbon nanosheets with sublimation sulfur. The S, N co-doping is responsible for the enlarged interlamellar spacing of 0.38 nm and abundant defect-introduced active sites. These structure features combined with the advantage of nanosheet are significant for activating sodium ion storage properties, endowing SNC with high Na+ storage capacity of 270 mAh g−1 at 0.1 A g−1 and 100 mAh g−1 at 1 A g−1 after 1000 cycles. More importantly, the kinetic analysis is carried out to illustrate that S, N co-doping can improve the Na+ diffusion coefficient in carbon anode and enhance the ion storage. This work deepens the understanding on the boosting effect of heteroatoms dual-doping for the sodium ion storage of carbon materials, which conduces to development of advanced heteroatom doped carbon anodes for SIBs. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 868
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 149548837
- Full Text :
- https://doi.org/10.1016/j.jallcom.2021.159080