Graph theory model and mechanism analysis of carbon fiber paper conductivity in fuel cell based on physical structure.

The gas diffusion layer (GDL) is considered one of the most significant components in the proton exchange membrane fuel cell (PEMFC). Its electrical impedance is crucial to the performance of power generation for PEMFC. The study of the conduction mechanism of the GDL substrate-carbon fiber paper(CFP) treated with PTFE is still a considerable challenge. This work reveals that the type and number of contact points are direct factors that affect CFP through-plane resistance. The CFP resistance along the through-plane direction is a function of the contact point density inside CFP, rather than traditional loading pressure. Based on the structural characteristics of CFP, a graph theory model that can express the complex three-dimensional structure and anisotropy of CFP is constructed instead of the finite element model or formula model—using the characterization of the distribution of PTFE in the CFP section. The accuracy of model prediction for the CFP resistance of 0 wt% and 20 wt% PTFE can reach 95% and 90%, respectively. This study provides a fundamental basis for the design and processing of CFP with lower electrical loss and is of great significance for further improving the power generation efficiency of PEMFC. Image 1 • A mechanism to explain the essential effect of PTFE on the conduction is proposed. • PTFE affects electrical resistance by changing the contact state of carbon fibers. • Graph theory model can be well used to simulate the conductivity of carbon paper. • There is huge potential for the reduction of electrical resistance in carbon paper. [ABSTRACT FROM AUTHOR]