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Carbon-Carbon Bond Activation by Rhodium(I) in Solution. Comparison of sp...-sp... vs sp...-sp...

Authors :
van der Boom, Milko E.
Liou, Shyh-Yeon
Source :
Journal of the American Chemical Society. 12/30/98, Vol. 120 Issue 51, p13415. 7p. 9 Diagrams, 1 Chart.
Publication Year :
1998

Abstract

Deals with a study that reported a system which allows the direct observation of an oxidative addition of a strong sp...-sp... Ar-Et bond to Rh(I), affording an unsaturated Rh(III)-ethyl complex. Transition metal insertion into strong carbon-carbon single bonds in solution; Details related to the mechanism of the reactions; Preparation of substrates.

Subjects

Subjects :
*RHODIUM
*CHEMICAL bonds

Details

Language :
English
ISSN :
00027863
Volume :
120
Issue :
51
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
1487644
Full Text :
https://doi.org/10.1021/ja982345b