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Catalytic Photoredox Allylation of Aldehydes Promoted by a Cobalt Complex.
- Source :
-
Advanced Synthesis & Catalysis . 2/16/2021, Vol. 363 Issue 4, p1105-1111. 7p. - Publication Year :
- 2021
-
Abstract
- The preparation of homoallylic alcohols by addition of organometallic allyl compounds to carbonyls is an important strategy in organic chemistry. Allylating organometallic cobalt species can be generated employing stoichiometric quantities of Zn acting as reductant. To avoid the employment of stoichiometric amount of Zn, we have developed an allylation reaction of aromatic and aliphatic aldehydes promoted by photoredox catalysis in the presence of a cobalt complex, and we present herein a full account of our research. In the presence of the abundant CoBr2 (10 mol %), 4,4′‐di‐tert‐butyl‐2,2′‐dipyridyl (dtbbpy, 10 mol %), allyl acetate (3 equiv.), [Ir(dtbbpy)(ppy)2]PF6 (ppy=2‐phenylpyridine, 2 mol %), and N,N‐diisopropylethylamine (4 equiv.), an allylation of aldehydes is taking place, in moderate to good yields. Substrates scope, limitations, and photophysical investigations of this new process are reported. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALLYLATION
*COBALT
*ALLYL compounds
*ALDEHYDES
*ORGANIC chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 16154150
- Volume :
- 363
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Advanced Synthesis & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 148755756
- Full Text :
- https://doi.org/10.1002/adsc.202001250