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SYNTHESIS, CRYSTAL STRUCTURE AND FLUORESCENT PROPERTIES OF A NEW MONOCULAR ZINC(II) COMPLEX BASED ON 2,6-BIS{[(4-ISOPROPYLPHENYL) IMINO]ETHYL}PYRIDINE.
- Source :
-
Journal of Structural Chemistry . Jan2021, Vol. 62 Issue 1, p105-110. 6p. - Publication Year :
- 2021
-
Abstract
- A new monocular zinc(II) complex [Zn(L1)Cl2] (complex 1), where L1 stands for 2,6-bis{[(4-isopropylphenyl)imino]ethyl}pyridine is synthesized and characterized. Complex 1 crystallizes in the monoclinic crystal system in the P21/n space group with a = 10.941 Å, b = 15.918 Å, c = 16.199 Å, β = 107.60°, and Z = 4. L1 acts as a tridentate ligand and is coordinated to the Zn1 atom in a five-coordinated trigonal bipyramidal geometry. The thermogravimetric analysis suggests that complex 1 can be stable up to 351 °C. The study of the photoluminescent properties indicates that complex 1 shows intense metal-perturbed π–π* intraligand fluorescence in the solid state. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00224766
- Volume :
- 62
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Journal of Structural Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 148720321
- Full Text :
- https://doi.org/10.1134/S0022476621010121