Lead chlorine cluster assembled one-dimensional halide with highly efficient broadband white-light emission.

Authors :: Zhao, Jian-Qiang
Sun, Chen
Yue, Meng
Meng, Yan
Zhao, Xian-Mei
Zeng, Le-Ran
Chen, Guang
Yue, Cheng-Yang
Lei, Xiao-Wu
Source :: Chemical Communications. 2/4/2021, Vol. 57 Issue 10, p1218-1221. 4p.
Publication Year :: 2021
Abstract: One new type of hybrid lead halide of [DTHPE]2Pb3Cl10 has been synthesized and characterized containing a one-dimensional (1D) wavelike [Pb3Cl10]4− chain based on a corner-shared [Pb3Cl11] cluster. Remarkably, this cluster-based 1D chain displays intrinsic broadband white light emission with a high quantum efficiency of 19.45% exceeding those of previously reported typical two-dimensional perovskites. [ABSTRACT FROM AUTHOR]

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