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Role of the ancillary ligand in controlling the lysozyme affinity and electronic properties of terpyridine fac-Re(CO)3 complexes.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 1/28/2021, Vol. 50 Issue 4, p1197-1201. 5p. - Publication Year :
- 2021
-
Abstract
- The lysozyme binding affinity and the electronic properties of [ReX(CO)3(terpy-κ2N1,N2)] (X = Br− and triazolateCOOCH2CH3,CF3) were reported. The triazolate complex was prepared in a [3 + 2] cycloaddition click reaction. The bromo compound reacted with lysozyme affording adducts with Re(CO)3+ fragments, while the triazolate compound persisted. A red shift of the MLCT band of the triazolate compound in progressively less polar solvents may be due to the negative solvatochromism. [ABSTRACT FROM AUTHOR]
- Subjects :
- *LYSOZYMES
*POLAR solvents
*REDSHIFT
*RING formation (Chemistry)
*SOLVATOCHROMISM
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 50
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 148453183
- Full Text :
- https://doi.org/10.1039/d0dt04140h