Efficient separation of fluoride and graphite carbon in spent cathode carbon from aluminum electrolysis by mechanical activation assisted alkali fusion treatment.

• More than 95% of fluorine was separated from spent cathode carbon (SCC). • Mechanical activation significantly enhanced the alkali fusion treatment of SCC. • Simultaneous conversion of multiple fluorides was achieved under acid-free conditions. • Non-toxic and high-quality graphite carbon was separated from SCC. Spent cathode carbon (SCC) is the largest and most inevitable hazardous solid waste continuously discharged from the aluminum electrolysis industry. In this study, mechanical activation was used to assist alkali fusion treatment in dissociating toxic substances and recovering graphite carbon from SCC. The effect of mechanical activation (i.e., milling speed, ball-to-material mass ratio, and milling time) on the alkali fusion treatment was investigated. Its effect on the physicochemical properties of SCC–Na 2 CO 3 mixtures was also analyzed through particle size distribution, Brunauer-Emmett-Teller surface area analysis, scanning electron microscopy, X–ray diffraction and thermogravimetric analysis–differential scanning calorimetry. Results showed that mechanical activation enhanced the alkali fusion treatment by improving the physical separation of fluoride, the mixing uniformity and reaction contact area of SCC and Na 2 CO 3 , and promoting the conversion of Na 2 CO 3 to Na 2 O. The formation of agglomerates was the main reason that the carbon content of recovered graphite carbon and the fluoride ion leaching rate increased initially then decreased with the increment in mechanical activation conditions. Under optimal mechanical activation conditions, the carbon content of recovered graphite carbon and the fluoride ion leaching rate increased from 89.35% and 76.50% (non-activated sample) to 93.93% and 95.02%, respectively, indicating that mechanical activation assisted alkali fusion treatment effectively enhanced the separation efficiency of fluoride and graphite carbon. In addition, thermodynamic analysis of the alkali fusion treatment and characterization of recovered graphite carbon (under the optimal mechanical activation conditions) were performed. Results demonstrated that the simultaneous conversion of multiple fluorides (i.e., Na 3 AlF 6 and CaF 2) and oxidative decomposition of cyanide in SCC can be achieved via mechanical activation assisted alkali fusion treatment. These findings indicate that mechanical activation–assisted alkali fusion treatment is a promising method for the detoxification and utilization of SCC. [ABSTRACT FROM AUTHOR]