Bioinspired symmetrical and unsymmetrical diiron complexes for selective oxidation catalysis with hydrogen peroxide.

Authors :: Trehoux, Alexandre
Guillot, Régis
Clemancey, Martin
Blondin, Geneviεave;ve
Latour, Jean-Marc
Mahy, Jean-Pierre
Avenier, Frédéric
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry. 12/14/2020, Vol. 49 Issue 46, p16657-16661. 5p.
Publication Year :: 2020
Abstract: Two new symmetrical and unsymmetrical diiron(III) complexes were synthesized and characterized by X-ray diffraction analysis, mass spectrometry, UV-visible and Mössbauer spectroscopies. They proved to be good catalysts for alkene and alkane oxidation reactions by H2O2 in acetonitrile solution, and interesting effects of both the nature and the symmetry of the complexes were observed on catalysis in the presence of water. [ABSTRACT FROM AUTHOR]

Subjects :: *HYDROGEN oxidation
*MASS spectrometry
*ULTRAVIOLET-visible spectroscopy
*CATALYSIS
*ACETONITRILE
*MOSSBAUER spectroscopy

Language :: English
ISSN :: 14779226
Volume :: 49
Issue :: 46
Database :: Academic Search Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 147507395
Full Text :: https://doi.org/10.1039/d0dt03308a

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