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6-Nitro-4,7-dihydroazolo [1,5-a]pyrimidines: an alternative mechanism of formation and studies of alkylation.
- Source :
-
Chemistry of Heterocyclic Compounds . 2020, Vol. 56 Issue 11, p1465-1472. 8p. - Publication Year :
- 2020
-
Abstract
- The mechanism of a multicomponent reaction between aminoazoles, 1-morpholino-2-nitroalkenes, and benzaldehyde was studied in acidic medium. Performing the reaction in acetic acid led to the formation of 6-nitro-5-phenyl-4,5,6,7-tetrahydropyrazolo[1,5-a]-pyrimidines, which subsequently underwent a rearrangement. Reaction conditions were proposed for a multicomponent synthesis with trioxane, and the alkylation reactions of 4,7-dihydroazolo[1,5-a]pyrimidine nitro derivatives were optimized. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00093122
- Volume :
- 56
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Chemistry of Heterocyclic Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 147387926
- Full Text :
- https://doi.org/10.1007/s10593-020-02839-6