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Topological analyses and bond characterization of 1,3,5,7-tetra-tert-butyl-s-indacene: a weak Csp³-H···H-Csp²-type dihydrogen interaction.

Authors :
Chih-Chieh Wang
Ting-Hua Tang
Lai-Chin Wu
Yu Wang
Source :
Acta Crystallographica: Section A (Wiley-Blackwell). Sep2004, Vol. 60 Issue 5, p488-493. 6p. 5 Diagrams, 4 Charts.
Publication Year :
2004

Abstract

Topological analyses of experimental and theoretical calculated electron densities of 1,3,5,7-tetra-tert-butyl-s-indacene provide bond characterizations of the chemical bond and of the π-delocalization. A weak Csp³—H···H—Csp²type intramolecular dihydrogen interaction (DHI) is identified through this analysis. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
01087673
Volume :
60
Issue :
5
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section A (Wiley-Blackwell)
Publication Type :
Academic Journal
Accession number :
14719173
Full Text :
https://doi.org/10.1107/S0108767304015375