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1‐Vinyl‐3‐allyl Imidazolium Bromide as a New Corrosion Inhibitor for Carbon Steel in 1 M HCl Solution.

Authors :
Li, Meng
Chen, Yun
Yang, Wenzhong
Source :
ChemistrySelect. 11/20/2020, Vol. 5 Issue 43, p13511-13523. 13p.
Publication Year :
2020

Abstract

The performance of 1‐vinyl‐3‐allyl imidazolium bromide ([VAIM][Br]) for inhibiting the corrosion of carbon steel in 1 M HCl solution from 298 K to 338 K was assessed. Electrochemical impedance spectroscopy (EIS) measurements proved that the inhibition efficiency (η) of [VAIM][Br] was as high as 95 %, and after immersion of 144 h, η still kept more than 90 %. Polarization curve verified that [VAIM][Br] acted as a mixed‐type inhibitor and adsorption of [VAIM][Br] was found to obey Langmuir adsorption isotherm. Molecular dynamic simulations suggested that the addition of vinyl group increased interaction energy between [VAIM]+ and (0 0 1) plane of Fe from 43.92 kcal mol−1 to 71.98 kcal mol−1. Liquid chromatography‐mass spectrometry (LC‐MS) and UV‐vis spectrum demonstrated that [VAIM][Br] and Fe atom can form stable complex (Fe2(VAIM)2Br4), which hindered the corrosion of carbon steel. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
23656549
Volume :
5
Issue :
43
Database :
Academic Search Index
Journal :
ChemistrySelect
Publication Type :
Academic Journal
Accession number :
147107078
Full Text :
https://doi.org/10.1002/slct.202000446