Recent advances in VOC elimination by catalytic oxidation technology onto various nanoparticles catalysts: a critical review.

• Selection of various nanoparticle catalysts is analyzed on the basis of VOC sorts. • The catalyst performance metric is unified for comparison among different studies. • VOC oxidation mechanisms based on experimental and theoretical data are summarized. • Integrating thermocatalysis with photocatalysis for VOC elimination is emphasized. Volatile organic compounds (VOCs) with the properties of volatility, toxicity and diffusivity pose a serious threat to human health and eco-environment. Catalytic oxidation technology has been considered as a highly efficient option for the treatment of VOCs. This review systematically summarizes the recent processes and advances on catalytic elimination of VOCs over nanoparticles catalysts. Firstly, catalytic performances of catalysts for VOC degradation are evaluated and compared on the basis of unified performance metrics. Secondly, catalytic mechanisms of VOC oxidation, based on experimental and theoretical studies, are systematically introduced. Then, catalytic reactors employed in VOC elimination processes are summarized. In particular, photothermocatalysis by integrating (thermo)catalysis with photocatalysis is also elucidated. Lastly, the perspectives to the scientific issues and challenges faced, as well as the future outlooks are proposed. Collectively, this review will provide theoretical and experimental foundation for rational fabrication and application of nanoparticles catalysts toward VOC elimination in future. [ABSTRACT FROM AUTHOR]