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Rhodium-catalyzed coupling of arenes and fluorinated α-diazo diketones: synthesis of chromones.
- Source :
-
Chemical Communications . 11/7/2020, Vol. 56 Issue 86, p13169-13172. 4p. - Publication Year :
- 2020
-
Abstract
- Rhodium(III)-catalyzed C–C coupling of heteroarenes and fluorinated α-diazo diketones has been realized for the facile synthesis of 3-arylchromones. The reaction proceeds via chelation-assisted C–H activation, carbene insertion, and uncatalyzed intramolecular nucleophilic aromatic substitution, with C–F cleavage being accommodated in the nucleophilic aromatic substitution step. Three classes of heteroarenes have been defined with decent functional group tolerance. [ABSTRACT FROM AUTHOR]
- Subjects :
- *KETONES
*HETEROARENES
*FUNCTIONAL groups
*RHODIUM
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 56
- Issue :
- 86
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 146704159
- Full Text :
- https://doi.org/10.1039/d0cc05664b